Utilization of Cyclodextrins in Gas Chromatography: Preparation of Capillary Columns with Cyclodextrin Stationary Phases

Authors

  • D. Kačeriaková Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technonoly, Bratislava, Slovakia
  • I. Špánik Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technonoly, Bratislava, Slovakia

Keywords:

cyclodextrins, gas chromatography, chiral stationary phases, enantiomers

Abstract

The columns are prepared by anchoring a cyclodextrin derivative in (polysiloxanes or ionic liquids) to inner capillary surface by physicochemical interactions. The cyclodextrine derivative and solvent polarity are the main factors influencing the efficiency and enantioselectivity of the columns. Alternatively, a cyclodextrin derivative copolymers is covalently attached to polysiloxane. This procedure enabled the column application at both lower and higher temperatures. Another method uses two or more independent chiral selectors, either dissolved in or bonded to an achiral solvent.

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Published

2014-05-15

How to Cite

Kačeriaková, D., & Špánik, I. (2014). Utilization of Cyclodextrins in Gas Chromatography: Preparation of Capillary Columns with Cyclodextrin Stationary Phases. Chemické Listy, 108(5), 462–469. Retrieved from http://ww-w.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/503

Issue

Vol. 108 No. 5 (2014)

Section

Articles